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Most chiral molecules arise from carbons being bonded to 4 different atoms, which are called sterocenters. The makes the molecule have a different mirror image that cannot arise from simple rotation. But, you can have chiral molecules not from stereocenters. You can have chirality that doesn't come from a single point in the molecule. It comes from some global property.The classic example is helicene, which doesn't have any stereocenters, but has chirality because of hits helical structure. This
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